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Beilstein J. Org. Chem. 2018, 14, 1370–1377, doi:10.3762/bjoc.14.115
Graphical Abstract
Figure 1: Cryptands with 1,3,5-triphenylbenzene (1) and 2,4,6-triphenyl-1,3,5-triazine (2) aromatic reference...
Scheme 1: Synthesis of cryptand 2.
Figure 2: NMR spectra of cryptand 2: top, 1H NMR; bottom, 13C NMR.
Figure 3: Chemical shift changes of the reference signal (belonging to the more deshielded protons of the p-p...
Figure 4: The equilibrium geometry structure of cryptand 2 having 2,4,6-triphenyl-1,3,5-triazine caps.
Figure 5: The equilibrium geometry structures of the cryptand–anthracene (a) and cryptand–pyrene (b) host–gue...
Figure 6: The equilibrium geometry structure of the cryptand 2–1,5-dihydroxynaphthalene host–guest complex.
Figure 7: The inclusion dynamics of the anthracene in the cavity of the cryptand for different constrained di...